73.Kaluarachchige
Don, U. I.; Buddhika Chandima, A. M.; Gelman, D.; Lord, R. L.; Groysman, S. Design and reactivity of early-late bimetallics as structural and functional models of Mo Cu CODH. Comments Inorg. Chem. 2024, doi:10.1080/02603594.2023.2298366
72.Kaluarachchige
Don, U. I.; Palmer, Z.; Ward, C. L.; Lord, R. L.; Groysman, S. Combining [MoVIO3] and [M0(CO)3] M=(Mo,Cr) fragments
within the same complex: synthesis and reactivity of the single oxo-
bridged heterobimetallics supported by xanthene-based
heterodinucleating ligands. Inorg. Chem. 2023, 62, 15063 - 15075.
71. Wannipurage,
D.; D'Anjello, S.; Pappalardo, D.; Kulathungage, L. W.; Ward,
C. L.; Anderson, D. P.; Groysman, S.; Mazzeo, M. Simple magnesium
alkoxides: synthesis, molecular structure, and catalytic behaviour in
the ring-opening polymerization of lactide and macrolactones and in the
copolymerization of maleic anhydride and propylene oxide. Dalton Trans. 2023, 52, 8077-8091.
70. Dissanayake, A. I.; Hollingsworth, T. S.; Madarang, E.; Hamilton, P. N.; Ward,
C. L.; Groysman, S. "Catch-store-release" strategy for the
stabilization of 4,4'-Methylene Diphenyl Diisocyanate (4,4'-MDI). Chem. Eur. J. 2023, 29, e202300924.
69. Kaluarachchige
Don, U. I.; Almaat, A. S.; Ward, C. L.; Groysman, S. Studies relevant
to the functional model of Mo-Cu CODH: in situ reactions of Cu(I)-L
complexes with Mo(VI) and synthesis of stable structurally
characterized heterotetranuclear MoVI2CuI2 Complex. Molecules 2023, 28, 3644.
68. Blasczak, V.; Mckinnon, M.; Suntrup, L.; Aminudin,
N. A.; Reed, B.; Groysman,
S.; Ertem, M. Z.; Grills, D. C.; Rochford, J. Steric and lewis basicity
influence of the second coordination sphere on electrocatalytic CO2
reduction by manganese bipyridyl complexes. Inorg. Chem. 2022, 61, 15784-15800.
67. Kurup, S. S.; Woodland, N. M.; Lord, R. L.; Groysman,
S. Aziridination reactivity of a manganese(II) complex with a bulky chelating bis(alkoxide) ligand. Molecules 2022, 27, 5751.
66. Kurup, S. S.; Groysman,
S. Catalytic synthesis of azoarenes via metal-mediated nitrene coupling. Dalton Trans. 2022, 51, 4577-4589. 
65. Dissanayake, A. I.; Hollingsworth, T. S.; Kurup, S. S.; Wannipurage,
D.; Hamilton, P. N.; Lord, R. L.; Groysman,
S. Synthesis, electronic structures, and reactivity of mononuclear and
dinuclear low-valent molybdenum complexes in iminopyridine and
bis(imino)pyridine ligand environments. J. Inorg. Biochem. 2022, 230, 111744. 
64. Kurup, S. S.; Nasser, S.; Ward, C. L.; Groysman, S. Synthesis and structure of a new bulky bis(alkoxide) ligand on a terphenyl platform. Acta Crystallogr. E: Crystallogr. Commun. 2022, 78, 92-96. 
63. Balch,
A.; Everett, G.; Power, P. P.; Armstrong, W. H.; Kovacs, J.; Stack,
T. D. P.; Donahue, J. P.; Gray, T. G.; Groysman, S.; Deng, L. Richard Hadley Holm: A remembrance and a tribute. Comments. Inorg. Chem. 2021, 1-48.
62. Wannipurage,
D.; Kurup, S. S.; Groysman, S. Heterocoupling of different aryl
nitrenes to produce asymmetric azoarenes using iorn-alkoxide catalysis
and investigation of the cis-trans isomerism of selected bulky
asymmetric azoarenes. Organometallics 2021, 40, 3637-3644.
61. Kaluarachchige Don, U. I.; Kurup, S. S.; Hollingsworth, T. S.; Ward, C. L.; Lord, R. L.; Groysman, S. Synthesis and Cu(I)/Mo(VI) reactivity of a bifunctional heterodinucleating ligand on a xanthene platform. Inorg. Chem. 2021, 60, 14655-14666. 
60. Groysman, S.; Grass, A. Alkoxide ligands, In Comprehensive Coordination Chemistry III, Constable, E. C.; Parkin, G.; Que, L., Jr, Eds, Elsevier 2021, 158-177.
59. Grass, A.; Kulathungage, L. W.; Wannipurage,
D.; Yousif,
M.; Ward, C. L.; Groysman, S. Synthesis, characterization, and alkoxide transfer reactivity of dimeric Tl2(OR)2 complexes. Dalton Trans. 2021, 50, 2501-2509.
58. Grass, A.; Bellow, J. A.; Morrison, G.; zur Loye, H.-C.;
Lord, R. L.; Groysman, S. One electron reduction transforms high-valent
low-spin cobalt alkylidene into high-spin cobalt(II) carbene radical. Chem. Commun. 2020, 56, 8416-8419.
57. Wannipurage,
D.; Hollingsworth,
T. S.; Santulli, F.; Cozzolino, M.; Lamberti, M.; Groysman, S.; Mazzeo,
M. Synthesis of a mononuclear magnesium bis(alkoxide) complex and its
reactivity in the ring-opening copolymerization of cyclic anhydrides
with epoxides. Dalton Trans. 2020, 2715-2723.
56. Kurup,
S. S.; Staples, R. J.; Lord, R. L.; Groysman, S. Synthesis of
chromium(II) complexes with chelating bis(alkoxide) ligand and their
reactions with organoazides and diazoalkanes. Molecules 2020, 25, 373.
55. Grass, A.; Wannipurage,
D.; Lord, R. L.; Groysman, S. Group-transfer chemistry at transition
metal centers in bulky alkoxide ligand environments. Coord. Chem. Rev. 2019, 400, 1-16.
54. Kurup, S. S.; Wannipurage, D.; Lord, R. L.; Groysman, S. Tying the alkoxides together: an iron complex of
a new chelating bulky bis(alkoxide) demonstrates
selectivity for coupling of non-bulky aryl nitrenes. Chem. Commun. 2019, 55, 10780-10783.
53. Grass, A.; Stoian S. A.;
Lord, R. L.; Groysman, S. Transition metal-mediated reductive coupling of diazoesters. Chem. Commun. 2019, 55, 8458-8461.
52. Grass, A.; Dewey. N. S.;
Lord, R. L.; Groysman, S. Ketenimine Formation Catalyzed by a High Valent Cobalt Carbene in Bulky Alkoxide Ligand Environment. Organometallics 2019, 38, 962-972.
51. Hollingsworth,
R. L.; Hollingsworth, T. S.; Groysman, S. Synthesis and Reactivity of
Bimetallic Systems Tethered with a 4,5-Diaminoxanthene Linker. In Catalysis by Metal Complexes and Nanomaterials: Fundamentals and Applications; ACS Symposium Series 1317; American Chemical Society: Washington, DC, 2019; pp 1-18.
50. Hollingsworth,
R. L.; Beattie, J. W.; Grass, A.; Martin, P. D.; Groysman, S.; Lord, R.
L. Reactions of Dicobalt Octacarbonyl with Dinucleating and Mononucleating Bis(imino)pyridine Ligands. Dalton Trans. 2018, 47, 15353-15363.
49. Yousif,
M.; Wannipurage, D.; Huizenga, C. D.; Washnock-Schmid, E.; Peraino, N.
J.; Ozarowski, A.; Stoian, S. A.; Lord, R. L.; Groysman, S. Catalytic
Nitrene Homocoupling by an Iron(II) Bis(alkoxide) Complex: Bulking Up
the Alkoxide Enables a Wider Range of Substrates and Provides Insight
into the Reaction Mechanism. Inorg. Chem. 2018, 57, 9425-9438.
48. Hollingsworth,
T. S.; Hollingsworth, R. L.; Lord, R. L.; Groysman, S. Cooperative
Bimetallic Reactivity of a Heterodinuclear Molybdenum-Copper model of
Mo-Cu CoDH. Dalton Trans. 2018, 47, 10017-10024.
47.
Hollingsworth, T. S.; Hollingsworth, R.
L.; Rosen, T.; Groysman, S. Zinc Bimetallics
Suppored by a Xanthene-Bridged Dinucleaing
Ligand: Synthesis, Characterization, and Lactide
Polymerization Studies. RSC
Adv. 2017, 7, 41819-41829.
46.
Reed, B. R.; Yousif, M.; Lord, R. L.;
McKinnon, M.; Rochford, J.; Groysman, S.
Coordination Chemistry and Reactivity of
Bis(aldimino)pyridine Nickel Complexes in Four
Different Oxidation States. Organometallics
2017, 36, 582-593.
45.
Hollingsworth,
R. L.; Bheemaraju, A.; Lenca, N.; Lord, R. L.; Groysman, S. Divergent
Reactivity of a New Dinuclear Xanthene-Bridged Bis(iminopyridine)
di-Nickel Complex with Alkynes. Dalton
Trans. 2017, 46, 5605-5616.
44.
Narayanan, R.; McKinnon, M.; Reed, B. R.;
Ngo, K. T.; Groysman, S.; Rochford, J. Ambiguous
Electrocatalytic CO2 Reduction Behaviour of a
Nickel Bis(aldimino)pyridine Pincer Complex. Dalton
Trans. 2016, 45, 15285-15289.
43.
Bellow, J. A.; Stoian, S. A.; Van Tol,
J.; Ozarowski, A.; Lord, R. L.; Groysman, S.
Synthesis and Characterization of a Stable
High-Valent Cobalt Carbene Complex. J.
Am. Chem. Soc. 2016, 138,
5531-5534.
42.
Yousif, M.; Cabelof, A. C.; Martin, P.
D.; Lord, R. L.; Groysman S. Synthesis of a
Mononuclear, Non-Square-Planar Chromium(II)
Bis(alkoxide) Complex and its Reactivity Toward
Organic Carbonyls and CO2. (Special
Issue: New Talent: Americas), Dalton
Trans. 2016, 45, 9794-9804.
See Maryam's interview that describes her work here Video
41.
Beattie, J. W.; SantaLucia, D. J.; White,
D. W.; Groysman. S. Oxalate- Templated Synthesis
of Di-Zinc Macrocycles. Inorg.
Chim. Acta. 2017, 460, 8-16.
40.
Bellow, J. A.; Yousif, M.; Groysman, S. Discrete
Complexes of 3d Metals with Monodentate Bulky
Alkoxide Ligands and Their Reactivity in Bond
Activation and Bond Formation Reactions. Comments
Inorg. Chem. 2015, 36, 92-122.
39.
Yousif, M.; Tjapkes, D.J.; Lord, R.L.; Groysman,
S. Catalytic Formation of Asymmetric
Carbodiimides at Mononuclear Chromium (II/IV)
Bis(alkoxide) Complexes. Organometallics 2015,
34, 5119
- 5128.
38.
Bellow, J. A.; Yousif, M.; Fang, D.; Kratz, E.
G.; Cisneros, G. A.; Groysman, S. Synthesis and
Reactivity of 3d Metal Complexes with the Bulky
Alkoxide Ligand [OCtBu2Ph].
Inorg. Chem. 2015, 54, 5624-
5633.
37.
Bellow, J. A.; Yousif, M.; Cabelof, A. C.; Lord,
R.L.; Groysman, S. Reactivity Modes of an Iron
Bis(alkoxide) Complex with Aryl Azides:
Catalytic Nitrene Coupling vs Formation of
Iron(III) Imido Dimers. Organometallics 2015,
34, 2917-2923.
36.
Reed, B.R.; Stoian, S.A.; Lord, R.L.; Groysman
S. The Aldimine Effect in Bis(imino)Pyridine
Complexes: Non-Planar Nickel(I) Complexes of a
Bis(aldimino)pyridine Ligand. Chem.
Commun. 2015, 51, 6496-6499.
35.
Bheemaraju, A.; Beattie, J.W.; Danylyuk, Y.;
Rochford, J.; Groysman S. Synthesis, Structures,
and Reactivity of Copper(I) Complexes Supported
by a Rigid Dinucleating Ligand. Eur. J.
Inorg. Chem. 2014, 34, 5865-5873.
34.
Beattie, J. W.; White, D.S.; Bheemaraju,
A.; Martin, P. D.; Groysman, S. Recyclable
Chemosensor for Oxalate Based on Bimetallic
Complexes of a Dinucleating Bis(iminopyridine)
Ligand. Dalton Trans. 2014, 49, 7979-7986.
33.
Bellow, J. A.; Martin, P. D.; Lord, R.
L.; Groysman, S. Reductive Coupling of Azides
Mediated by an Iron(II) Bis(alkoxide) Complex. Inorg.
Chem. 2013, 52, 12335
-12337.
32.
Bellow, J. A.; Fang, D.; Kovacevic, N.;
Martin, P. D.; Shearer, J.; Cisneros, G. A.;
Groysman, S. Novel Alkoxide Cluster Topologies
Featuring Rare Seesaw Geometry at Transition
Metal Centers. Chem. Eur. J.
2013, 19, 12225-12228.
31. Bheemaraju
A.; Beattie, J. W.; Tabasan, E. G.;
Martin, P. D.; Lord, R. L.; Groysman, S.
Steric and Electronic Effects in the Formation
of Carbon Disulfide Reactivity of Dinuclear
Nickel Complexes Supported by Bis(iminopyridine)
Ligands. Organometallics 2013, 32, 2952-2962.
30. Chambers,
M. B.; Groysman, S.; Villigran, D.; Nocera, D.
G.; Iron in a Tris(alkoxide) Ligand
Enviroment. Inorg. Chem. 2013, 52,
3159-3169.
29. Bheemaraju
A.; Beattie, J. W.; Lord, R. L.;
Martin, P. D.; Groysman, S. Carbon Disulfide
Binding at Dinuclear and Mononuclear Nickel
Complexes Ligated by a Redox-Active Ligand:
Iminopyridine Serving as an Accumulator of Redox
Equivalents for the Activation of Heteroallenes.
Chem. Commun. 2012, 48,
9595-9597.
28. Bheemaraju
A.; Lord, R. L.; Müller, P.; Groysman, S. Difference in the Reactivities of
H- and Me-Substituted Dinucleating
Bis(iminopyridine) Ligands with Nickel(0). Organometallics
2012, 31, 2120-2123.
27. Groysman,
S.; Villagrán, D.; Freedman, D. E.; Nocera, D. G. Dinitrogen Binding at
Vanadium in the Tris(alkoxide) Ligand
Environment. Chem. Commun. 2011, 47,
10242-10244.
26. Groysman, S.;
Villagrán, D.; Nocera, D. G.
Pseudo-tetrahedral d0, d1, and d2 Metal-Oxo
Cores Within a Tris(alkoxide) Platform. Inorg.
Chem. 2010, 49,
10759-10761.
25. Groysman,
S.; Majumdar, A.; Zheng, S.-L.; Holm, R.H. Reactions of Monodithiolene
Tungsten(VI) Sulfido Complexes with Copper(I) in
Relation to the Structure of the Active Site of
Carbon Monoxide Dehydrogenase. Inorg. Chem.
2010, 49, 1082-1089.
24. Groysman,
S.; Holm, R. H. Biomimetic
Chemistry of Iron, Nickel, Molybdenum, and
Tungsten In Sulfur-Rich Protein Sites. Biochemistry
2009, 48, 2310-2320.
23. Groysman,
S., Holm, R. H. A Series of
Mononuclear Quasi-Two-Coordinate Copper(I)
Complexes Employing a Sterically Demanding
Thiolate Ligand. Inorg. Chem. 2009,
48, 621-627.
22. Groysman,
S., Wang, J. - J., Tagore, R., Lee,
S. C., Holm, R. H. A Biomimetic Approach to
Oxidized Sites in the Xanthine Oxidoreductase
Family: Synthesis and Stereochemistry of
Tungsten(VI) Analogue Complexes. J. Am.
Chem. Soc. 2008, 130,
12794-12807.
21. Wang, J. - J.; Groysman,
S.; Lee, S. C.; Holm, R. H.
Synthesis of Structural Analogues of the
Oxidized Sites in the Xanthine Oxidoreductase
Enzyme Family. J. Am. Chem. Soc. 2007,
129, 7512-7513.
20. Groysman,
S.; Holm, R. H.. Synthesis and
Structures of Bis(dithiolene) Tungsten (IV,VI)
Thiolate and Selenolate
Complexes: Approaches to the Active
Sites of Molybdenum and Tungsten Formate
Dehydrogenases. Inorg. Chem. 2007,
46, 4090-4102.
19. Groysman, S.;
Sergeeva, E.; Goldberg, I.; Kol, M. Zinc
Complexes of the Amine Mono(phenolate) [NOO2]
Ligands: Controlling Coordination Modes by Bulk
of Phenolate Substituents. Eur. J. Inorg.
Chem. 2006, 14, 2739-2745
18. Kol, M., Segal, S.,
Groysman, S. 2008. Stereocontrol
in the Polymerization of C4+ α-olefin
Monomers. In Stereoselective
Polymerization with Single-Site Catalysts L.
S. Baugh, J.–A. Boca Raton, FL.
17. Gendler, S., Groysman,
S., Goldschmidt, Z., Shuster, M., and
Kol, M.. Polymerization of 4-methylpentene and
Vinylcyclohexane by the Amine Bis(phenolate)
Group IV catalysts. J. Polym. Sci., Part A:
Polym. Chem. 2006,
44, 1136-1146.
16. Groysman,
S.; Sergeeva, E.; Goldberg, I.; and
Kol, M. Group IV Complexes of a Tetradentate
Amine Mono(phenolate) Ligand: a Second Sidearm
Donor Stabilizes Cationic Species. Inorg.
Chem. 2005, 44,
8188-8190.
15. Yeori, A.; Groysman,
S.; Goldberg, I.; and Kol, M.;
2005. Diastereoisomerically–Selective
Enantiomerically–Pure Titanium Complexes of
Chiral Salan Ligands. Inorg. Chem. 2005,
44, 4466-4467.
14. Groysman, S.;
Goldberg, I.; Kol, M.; and Goldschmidt, Z.
Vanadium(III) and Vanadium(V) Amine
Tris(phenolate) Complexes. Inorg. Chem. 2005,
44, 5073-5080.
13. Groysman, S.;
Sergeeva, E.; Goldberg, I.; and Kol. M.,
Salophan complexes with Group IV Metals.
Eur. J. Inorg. Chem. 2005,
2480-2485.
12. Groysman, S.;
Goldberg, I., Kol, M., Genizi, E., and
Goldshmidt, Z. Exploring Routes to Tantalum (V)
Alkyl and Alkylidene Complexes Supported by the
Amine Tris(Phenolate) ligands. Adv. Syn.
Cat. 2005, 347,
409-415.
11. Groysman,
S.; Tshuva, E.; Goldberg, I.; Kol,
M.; Goldschmidt, Z.; and Shuster, M. Diverse
Structure-Activity Trends in the Amine
Bis(phenolate) Titanium Polymerization
Catalysts. Organometallics 2004,
23, 5291
10. Groysman, S.;
Segal, S.; Goldberg, I.; Kol, M.; and
Goldschmidt, Z. Ta(V) Complexes of a Bulky Amine
Tris(phenolate) Ligand: Steric Inhibition vs.
Chelate Effect. Inorg. Chem. Commun. 2004,
7, 938-941.
9. Groysman,
S.; Goldberg, I.,; Kol, M.; Genizi,
E.; and Goldschmidt, Z. Tribenzyl Ta(V)
Complexes of Amine Bis(phenolate) Ligands:
Investigation of α-Abstraction vs. Ligand
Backbone β-Abstraction Paths.
Organometallics 2004, 23,
1880-1890.
8. Yeori, A.;
Gendler, S.; Groysman, S.;
Goldberg, I.; and Kol. M. Salalen: a Hybrid
Salan/Salen Tetradentate [ONNO]–Type Ligand and
Its Coordination Behavior with Group IV Metals.
Inorg. Chem. Commun. 2004,
7, 280-282.
7. Groysman,
S.; Goldberg, I.; Kol, M.; and
Goldschmidt Z. Pentabenzyltantalum:
Straightforward Synthesis, X-ray Structure and
Application in the Synthesis of [O2N]TaBn3-Type
and [O3N]TaBn2-Type complexes. Organometallics
2003, 22, 3793-3795.
6. Groysman, S.;
Goldberg, I.; Kol, M.; Genizi, E.; and
Goldschmidt Z. From THF to Furan: Activity
Tuning and Mechanistic Insight via Sidearm Donor
Replacement in Group IV Amine Bis(phenolate)
Polymerization Catalysts. Organometallics
2003, 22, 3013-3015.
5. Groysman, S.;
Tshuva, E. Y.; Reshef, D.; Gendler, S.;
Goldberg, I.; Kol, M.; Goldschmidt, Z.; Shuster,
M.; and Lidor, G. High-Molecular Weight Atactic
Polypropylene prepared by Zirconium Complexes of
an Amine Bis(phenolate) Ligand. Isr. J.
Chem. 2003, 42,
373-381.
4. Groysman, S.;
Goldberg, I.; Kol, M.; Genizi, E.; and
Goldschmidt, Z. Group IV complexes of an Amine
Bis(phenolate) Ligand Featuring a THF Sidearm
Donor: From Highly Active to Living
Polymerization Catalysts of 1-Hexene Inorg.
Chim. Acta 2003,
345, 137-144. (Protagonists in Chemistry:
R. R. Schrock Issue)
3. Bergman, S.; Reshef,
D.; Groysman, S.; Goldberg,
I.; and Kol, M., Dibenzoeilatin: A Novel Ligand
Exhibiting Remarkable Complementary π-π Stacking
Interactions. Chem. Commun. 2002,
2374-2375.
2. Groysman, S.;
Segal, S.; Shamis, M.; Goldberg, I.; Kol,
M.; Goldschmidt, Z.; and Hayut-Salant, E.
Tantalum(V) Complexes of an Amine Triphenolate
Ligand: a Dramatic Difference in Reactivity
Between Two Labile Positions. J. Chem.
Soc., Dalton Trans. 2002,
3425-3426.
1. Tshuva, E. Y.;
Groysman, S.; Goldberg, I.;
Kol, M.; and Goldschmidt, Z. [ONXO]-Type Amine
Bis(phenolate) Zirconium and Hafnium Complexes
as Extremely Active 1-hexene Polymerization
Catalysts. Organometallics 2002,
21, 662-670.
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